MMO Titanium Electrodes for Water Treatment | Durable Coated Anodes
MMO titanium electrodes are used in industrial electrolysis, electroplating, wastewater treatment, hydrogen production, cathodic protection, and electrochemical disinfection systems. Compared to traditional graphite and lead alloy electrodes, MMO titanium electrodes offer higher current efficiency, longer service life, lower energy consumption, and corrosion resistance.
Baoji Shenao Metal Materials Co., Ltd. is a professional titanium electrode manufacturer, providing customized MMO titanium electrodes for global industrial electrochemical applications. Our products utilize a high-purity titanium substrate combined with advanced mixed metal oxide coatings, such as ruthenium-iridium, iridium-tantalum, platinum, and ruthenium-titanium systems.
Our MMO titanium electrodes are designed for stable operation under high current densities and harsh chemical environments. We can provide customized shapes, sizes, coating systems, and electrode structures according to different industry needs.
MMO titanium electrodes refer to titanium-based electrodes coated with a mixed metal oxide catalytic layer. The titanium substrate has high mechanical strength and corrosion resistance, while the MMO coating improves electrochemical activity and reduces oxygen evolution or chlorine evolution overpotential.
These electrodes are also known as:
MMO-coated titanium electrodes
Mixed metal oxide titanium anodes
Titanium anodes for electrolysis
DSA electrodes (size-stabilized anodes)
MMO titanium electrodes are widely used due to the following advantages:
Long service life
Excellent conductivity
Stable catalytic performance
Low consumable consumption rate
High current efficiency
Low maintenance cost
一. Working principle of MMO titanium electrodes
Electrochemical reaction mechanism
In an electrolysis system, current flows through the electrolyte to the MMO titanium electrode, causing an oxidation reaction on its surface.
The MMO coating catalytic layer reduces the reaction overpotential, improving efficiency and reducing energy consumption.
Coating Systems:
1. Chlorine Evolution Reaction (CER)
Applications:
Sodium hypochlorite generation
Seawater electrolysis
Electrolytic disinfection
Chlor-alkali systems
Recommended Coating:
Ruthenium-iridium coating
2. Oxygen Evolution Reaction (OER)
Applications:
Hydrogen electrolysis
Electroplating
Wastewater treatment
Electrochemical oxidation
Recommended Coating:
Iridium-tantalum coating
二. MMO Coating Systems
1. Ruthenium-iridium Coating
Ruthenium-iridium coated MMO titanium electrodes offer high chlorine evolution efficiency and low chlorine evolution potential.
Characteristics:
High catalytic activity
Chlorine generation efficiency
Strong corrosion resistance
Suitable for seawater environments
Applications:
Electrolytic chlorination
Swimming pool disinfection
Ballast water treatment
Sodium hypochlorite generator
2. Iridium-tantalum Coating
Iridium-tantalum coating is mainly used in oxygen evolution environments.
Features: High oxygen evolution efficiency
Long service life
Stable at high current densities
Excellent acid resistance
Applications: Hydrogen production by water electrolysis
Electroplating
Industrial wastewater treatment
Electrochemical oxidation
3. Platinum-coated titanium electrode
Platinum-coated titanium electrodes have high conductivity and high catalytic performance.
Features:
Low overpotential
High current efficiency
Strong oxidation resistance
Stable electrochemical performance
Applications:
Precious metal recovery
Electroplating
Laboratory electrolysis
High-precision electrochemical systems
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三. Advantages of MMO Titanium Electrodes
1. Long Service Life
Compared to graphite electrodes, MMO titanium electrodes can operate continuously for years under appropriate operating conditions.
The stable titanium matrix prevents structural deformation and improves durability.
2. High Current Efficiency
The MMO catalytic coating reduces energy loss during electrolysis, improving current efficiency and lowering operating costs.
3. Corrosion Resistance
Titanium exhibits excellent corrosion resistance, including:
Acid Corrosion
Alkali Corrosion
Seawater Corrosion
Chloride Ion Attack
MMO titanium electrodes are suitable for harsh industrial environments.
4. Low Energy Consumption
The mixed metal oxide coating reduces overpotential, lowering electrolytic cell voltage and power consumption.
This helps industrial users reduce electricity costs in continuous electrolysis operations.
5. Customizable
We can produce customized MMO titanium electrodes in various forms:
Plate
Mesh
Rod
Tube
Wire. Custom sizes and coating formulations are available upon request.
四.Technical Parameters of MMO Titanium Electrodes
|
Parameter |
Specification |
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Substrate Material |
Gr1 Titanium / Gr2 Titanium |
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Coating Type |
Ru-Ir / Ir-Ta / Pt |
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Titanium Thickness |
0.5–3.0 mm |
|
Current Density |
500–15000 A/m² |
|
Working Temperature |
≤85°C |
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pH Range |
1–14 |
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Coating Thickness |
8–15 μm |
|
Shape |
Plate, Mesh, Rod, Tube |
|
Service Life |
2–10 Years |
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Base Material Standard |
ASTM B265 |
五. Applications of MMO Titanium Electrodes
1. Water Treatment Industry
MMO titanium electrodes are used in electrochemical water treatment systems.
Applications
Industrial wastewater treatment
Electro-oxidation
COD removal
Ammonia nitrogen removal
Organic pollutant degradation
MMO titanium electrodes improve oxidation efficiency and water treatment performance, reducing chemical reagent consumption.
2. Hydrogen Production via Water Electrolysis
In hydrogen electrolysis systems, MMO titanium electrodes are used as oxygen evolution electrodes.
Advantages in Hydrogen Production
Stable oxygen evolution performance
Reduced energy consumption
Long-term operational stability
Used in alkaline electrolysis systems
Used in green hydrogen production projects and renewable energy hydrogen production systems.
3. Electroplating Industry
MMO titanium electrodes are used in:
Copper electroplating
Nickel electroplating
Zinc electroplating
Chromium electroplating
Precious metal electroplating
Compared to lead alloy anodes, MMO titanium electrodes improve electroplating efficiency and extend service life.
4. Electrolytic Sodium Hypochlorite Generator
Ruthenium-iridium coated MMO titanium electrodes are used in sodium hypochlorite generators.
Advantages
High chlorine evolution efficiency
Stable chlorine output
Less scaling
Long service life
Applications include:
Drinking water disinfection
Hospital disinfection systems
Food processing hygiene
Swimming pool disinfection
5. Cathodic Protection System
MMO titanium electrodes are used in impressed current cathodic protection systems.
Applications
Pipelines
Marine engineering
Offshore platforms
Storage tanks
Underground structures
Provides stable current output and long-term corrosion protection.
六. Industry Application Cases
1. Industrial Wastewater Treatment Project
A chemical plant required high-efficiency electrochemical oxidation equipment for wastewater treatment.
Solution
We provide:
Iridium-tantalum coated MMO titanium electrode
Titanium mesh structure
Customized current density design
Results
COD removal rate increased by 35%
Energy consumption reduced by 18%
Electrode lifespan exceeding 4 years
2. Seawater Electrolysis System
A marine engineering company required MMO titanium electrodes for seawater chlorination.
Solution
We provide ruthenium-iridium coated titanium electrodes optimized for chlorine evolution.
Results
Stable chlorine production
Excellent resistance to seawater corrosion
Good continuous operation performance
3. Hydrogen Electrolysis Project
A hydrogen energy company required long-life oxygen evolution electrodes for alkaline water electrolysis.
Solution
Customized iridium-tantalum coated MMO titanium electrode with high oxygen evolution activity.
Results:
Electrolyzer voltage decreased
Hydrogen production efficiency increased
Long-term operation stabilized
七. Why Choose Our MMO Titanium Electrodes?
1. Advanced Coating Technology
We employ precision thermal decomposition coating technology to ensure uniform catalyst layer distribution and strong coating adhesion.
2. Strict Quality Control
Each MMO titanium electrode undergoes the following processes:
Coating thickness testing
Surface testing
Current density testing
Electrochemical performance evaluation
3. OEM and Custom Production
We support:
Custom sizes
Custom current densities
Custom coating systems
Custom production based on provided drawings
4. Global Export Experience
Our MMO titanium electrodes are exported to:
Europe
Southeast Asia
Middle East
South America
North America
Applications cover water treatment, electrolysis, electroplating, and environmental protection industries.
Our Factory
Our Patents and Honors
八. Frequently Asked Questions about MMO Titanium Electrodes
What is the lifespan of an MMO titanium electrode?
The lifespan is typically 2 to 10 years, depending on current density, electrolyte composition, temperature, and coating type.
Which coating is suitable for chlorine evolution?
Ruthenium-iridium coatings are used for chlorine evolution applications, such as sodium hypochlorite production and seawater electrolysis.
Which coating is suitable for oxygen evolution applications?
Iridium-tantalum coatings are used in oxygen evolution environments, such as hydrogen electrolysis and wastewater treatment.
Can MMO titanium electrodes be customized?
Yes. We support customized sizes, coating formulations, electrode structures, and connection methods.
Which industries use MMO titanium electrodes?
Main industries include:
Water treatment
Hydrogen production
Electroplating
Electrochemical oxidation
Cathode protection
Electrolytic disinfection
九. Request a Quote for MMO Titanium Electrodes
Looking for high-performance MMO titanium electrodes for industrial electrolysis systems?
Contact Baoji Shenao Metal Materials Co., Ltd. to obtain:
Customized Electrode Solutions
Technical Support
Fast Quotes
OEM Manufacturing
Global Export Services
Our engineering team can recommend suitable MMO coating systems based on your electrolyte environment, current density, and application requirements.
Email: zh@baojiti.com.cn
WhatsApp: +86-13636825659
MMO Titanium Electrode Technology and Industry Knowledge
Technical Principles of MMO Titanium Electrodes
MMO titanium electrodes are mixed metal oxide catalytic coatings. They are formed by thermal decomposition on the surface of a titanium substrate. During electrolysis, the coating acts as an active catalytic layer, promoting electrochemical reactions and protecting the titanium substrate from passivation.
Compared to traditional graphite electrodes, MMO titanium electrodes maintain dimensional stability during long-term operation. They are known as dimensionally stable anodes.
Oxygen evolution reaction (OER) and chlorine evolution reaction (CYR) are two major electrochemical processes in industrial applications. Different MMO coating formulations are selected based on the reaction. Ruthenium-based coatings are commonly used for chlorine evolution electrolysis, while iridium-based coatings are suitable for oxygen evolution electrolysis.
Operating Environment of MMO Titanium Electrodes
MMO titanium electrodes are suitable for the following harsh industrial operating environments:
High chloride ion concentration
Acidic solutions
Alkaline electrolytes
Seawater systems
High current density electrolysis systems
Titanium has strong corrosion resistance, and MMO titanium electrodes perform excellently in long-term continuous electrolysis applications.
Application industries include:
Industrial wastewater treatment
Electrochemical oxidation
Electrolytic copper foil production
Chlor-alkali industry
Hydrogen electrolysis
Electro-sterilization systems
Different coating systems should be selected based on temperature, pH value, and electrolyte composition.
Platinum-coated titanium electrodes
Comparison of MMO Titanium Electrodes and Graphite Electrodes
Comparing MMO titanium electrodes with graphite electrodes, graphite electrodes offer several advantages.
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Comparison Item |
MMO Titanium Electrodes |
Graphite Electrodes |
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Service Life |
Long |
Short |
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Corrosion Resistance |
Excellent |
Moderate |
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Current Efficiency |
High |
Lower |
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Energy Consumption |
Lower |
Higher |
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Mechanical Strength |
Strong |
Fragile |
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Maintenance Frequency |
Low |
High |
Graphite electrodes are easily worn down during electrolysis, while MMO titanium electrodes maintain stable size and catalytic activity.
Comparison of MMO Titanium Electrodes and Lead Alloy Electrodes
Due to environmental issues and lower efficiency, lead alloy electrodes have been gradually replaced in many industries.
MMO titanium electrodes offer the following advantages:
Clean electrochemical process
Low risk of metal contamination
High energy efficiency
Long service life
Low maintenance costs
These advantages make MMO titanium electrodes an essential choice for modern industrial electrolysis systems.






















